The Prilezhaev reaction enables the epoxidation of alkenes by concerted oxygen atom transfer from a peracid, converting C=C bonds into epoxides. Discovered by Nikolai Prilezhaev in the early 20th century, the reaction proceeds through a single-step, stereospecific mechanism that preserves alkene geometry, forming the three-membered oxirane ring without discrete ionic intermediates. Learn. Review. Repeat.
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